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Matthew Followill is the lead guitar player in the band Kings Of Leon. The band is comprised of 3 brothers and one cousin (all named Followill of course).
Let's look at some of the gear and equipment that has been seen in Matthew's Kings Of Leon guitar rig. Please post a comment if you have any guitar, amp, or effect additions to make to the article.

Click the gear images for more info and specs at Musician's Friend
Guitars - Gibson Heritage Cherry ES-137

- Epiphone Sheraton II

- Gibson Les Paul Custom

Amps and Cabinets - Ampeg Reverberocket R-212R
Effects
Matthew has some pedals on the ground in front of him and many pedals in a rack that is controlled by a Ground Control.
- Voodoo Lab GCX Switcher and Ground Control (GCX is in the rack)  
- Line 6 Verbzilla (in the rack drawers)
 
- Dunlop crybaby(on the floor)

- BOSS ME-50 (in the rack drawers)

- Line 6 DL4 (in the rack drawers)

- Electro Harmonix POG (in the rack drawers)

- Digitech Whammy (in the rack drawers AND on the floor)

- Ernie Ball Volume Pedal (on the floor)

- MXR M-133 Micro Amp (in the rack drawers)

- Visual Sound Route 66 Overdrive Guitar Pedal (on the floor AND in the rack)

- Boss Super Shifter (in the rack drawers)

- Boss TU-2 (on the floor)
 
- DigiTech DigiVerb

- Eventide Harmonizer pedal (used on Come Around Sundown album)
 
Strings and Picks - D’Addario guitar strings 11's

- Dunlop Tortex .60mm guitar picks

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Comments
Pog+Lots of Reverb.....
For Arizona he uses the DL4 and verbzilla set to octo, and for Knocked Up and Charmer as others have said its the route 66, Whammy and boss RV5.
Hope that helps
I planning to buy a digiverb, but I would only use it for these songs, so if anyone knows if he uses his reverb pedals in these songs please let me know as quick as possible thanx '
musicradar.com/.../...
cheers.
I've heard people say "play harmonics" but there has got to be an effect pedal out there that can create that high pitched noise!!! I have a multi effects pedal I can do it with (set on a whammy setting), but it takes up a lot of room on my pedalboard, so eventually i'd like to get rid of it. Would a whammy pedal (the red digitech whammy pedal) create that sound??? Know of any others that would?